ICMCTF2012 Session E3-2/G2-2: Development, Characterization, and Tribology of Coatings for Automotive and Aerospace Applications

Tuesday, April 24, 2012 1:50 PM in Room Pacific Salon 1-2

Tuesday Afternoon

Time Period TuA Sessions | Abstract Timeline | Topic E Sessions | Time Periods | Topics | ICMCTF2012 Schedule

Start Invited? Item
1:50 PM E3-2/G2-2-1 In situ tribology of cold spray-deposited pure aluminum and Al-Al2O3 composite coatings
J.Michael Shockley, Richard Chromik, Holger Strauss (McGill University, Canada); Eric Irissou, Jean-Gabriel Legoux (National Research Council, Canada)
Cold sprayed aluminum coatings are valued for their good corrosion resistance, but their poor tribological performance limits their use in automotive and aerospace applications where wear resistance is also required. Hard phases such as Al2O3 may be co-sprayed along with aluminum powders to create Al-Al2O3 composite coatings with improved tribological performance. Traditional ball-on-flat tribometry prevents direct observation of the sliding interface during wear, meaning only ex situ analysis of wear surfaces and debris is possible. In the present study, an in situ tribometer with a transparent sapphire counterface was used for ball-on-flat testing of cold sprayed aluminum coatings deposited with up to 20 vol.% Al2O3 particles. Similar to the use of in situ tribometry for solid lubricants, the technique revealed details of metallic transfer film formation and detachment. It was found that in the Al-Al2O3 cold spray coatings, the transfer film was more stable as hard phase content increased, which was also correlated to increase in friction stability and decreased wear.
2:10 PM E3-2/G2-2-2 Thermal Spray Lubricious Oxide Coatings
Satish Dixit (Plasma Technology Inc., US); Osman Eryilmaz, Ali Erdemir (Argonne National Laboratory, US)

During the extreme conditions experienced in automotives and aerospace applications, oil-based lubricants break down at high temperatures. Under such conditions, conventional fluid lubricants either fail early or never are considered as an option. As a result, components of engines that are run at high temperatures to improve their fuel efficiency tend to wear rapidly and require replacement. One solution to extend bearing life is with the implementation of a low friction, high temperature stable, and low wear coatings to the component surface that can perform under extreme conditions. Solid lubricant coatings offer a solution for diverse applications exhibiting extreme and difficult running conditions. Although the most common dry-solid lubricants are graphite, MoS2, WS2, TaS2, and PTFE, they are limited in terms of their high temperature capabilities as well as their wear characteristics. Hence in this paper we propose novel thermal spray lubricious oxide coatings based on a crystal chemical approach. Different combinations of the oxide materials are chosen based on their ionic potential differences and plasma sprayed to a thickness of 150 to 200 microns. Their composition, microstructure and high temperature wear characteristics are reported in this paper.

2:50 PM E3-2/G2-2-4 High temperature abrasive systems
John Davenport, Robert (R.) Stearn (University of Cambridge, UK); Matthew Hancock (Rolls Royce, US); William Clegg (University of Cambridge, UK)

Increasing the efficiency of a gas turbine engine requires that any leakage of gas from the working gas path is minimized, of particular importance is leakage around the tips of high pressure (HP) turbine blades. This can be approached by using an abradable sealing system, where abrasive particles embedded in an anchor phase are fixed to the end of the turbine blade tip, and an abradable coating. The turbine blades cut a track through the abradable coating on the shroud, the abrasive particles protect the turbine blade from wearing away against the abradable.

However lifetimes of the current sealing system are unacceptably short, with oxidation of the abrasive and creep of the anchor phase being two major factors.

The abrasion behavior of various abrasives against a magnesium aluminate spinel abradable has been studied using a pin-on-disc abrasion rig at temperatures up to 1300 oC. It has been shown, even at the velocities of just a few metres per second, that abrasion causes fracture of the particles and frictional heating approximately consistent with predictions in the literature. At elevated temperatures and at these velocities it is shown that correcting for the difference in velocity predicts temperature changes about the melting point of the MCrAlY, and even close to that of the abrasive.

3:10 PM E3-2/G2-2-5 Customized Surface Technology for Innovative Automotive and Industrial Products
Tim Hosenfeldt, Yashar Musayev (Schaeffler Technologies GmbH & Co. KG, Germany)

Modern components and systems for automotive and industrial applications have to meet various requirements in multiple technical fields. Apart from properties that affect the part itself – like geometry, stiffness, weight or rigidity – the surface properties must be adjusted to the growing environmental requirements. This includes measures for corrosion and wear protection, for optimum electrical or thermal conductivity and for optical purposes. Beyond those, coatings are increasingly used to reduce the friction losses of car components, improve fuel efficiency and reduce CO2-emissions.

This article describes how to use surface technology as a modern design element for components and systems to enable the increasing requirements on market leading automotive and industrial products.

Therefore Schaeffler has developed and established a coating tool box for customized surfaces to apply the right solutions for all that needs and requests with the corresponding coating system made by PVD-/ PACVD-, spraying or electrochemical technology. For innovative products it is extremely important that coatings are considered as design elements and integrated in the product development process at a very early stage.

In this article tribological coatings are viewed within a holistic and design-oriented context. The latest developments of amorphous carbon coatings, its characteristics as well as the technical and economical effects of its use in combustion engines and industrial bearing applications are described.

The presented Triondur® amorphous carbon based coating systems (a-C:H; a-C:H:Me; a-C:H:X and ta-C) are excellent examples for customized tribological systems like bucket tappets, linear guidances and roller bearings.

Triondur® carbon coatings offer the following advantages:

• Super low friction with highest wear resistance.

• Customized surface energy.

• Optimized wetability and interaction with formulated engine oils.

• Low adhesion to the counterpart.

Close collaboration between designers and surface engineers is required in the future. Schaeffler delivers around 70 million high-quality PVD- and (PA)CVD-coated components (Triondur®) every year that enable outstanding applications, preserve resources and meet increasing customer requirements.

3:50 PM E3-2/G2-2-7 Ultra-fast Synthesis of Superhard Borides: A Paradigm Shift in Surface Engineering for Tooling and Automotive Applications
Ali Erdemir, Osman Eryilmaz (Argonne National Laboratory, US); Servet Timur (Istanbul Technical University, Turkey); Ozgenur Kahevcioglu (Argonne National Laboratory, US); Guldem Kartal (Istanbul Technical University, Turkey); Vivekanand Sista (Argonne National Laboratory, US)
During the last two decades, there has been considerable interest in the development and diverse utilization of novel coatings and surface treatments that can enhance efficiency, durability, and environmental compatibility of a variety of automotive and machine tool components. Among others, the development of DLC and other low-friction coatings has attracted the most attention mainly because of their unique abilities to provide much superior performance under severe tribological conditions. Tribological properties of mechanical components can also be improved by a variety of well-established surface treatments like nitriding, carburizing, and boriding. All of these methods are used extensively by today’s automotive industry despite being very time and energy consuming. In this talk, a novel super-fast surface treatment method called ultra-fast boriding will be introduced as a highly robust and low-cost alternative to current surface treatment and coating methods. New boriding process is capable of producing more than 90 micrometer thick boride layers in 30 minutes on a variety of steels and in the case of certain non-ferrous alloys, it is capable of producing ultra-thick and hard boride layers providing more than 45 GPa hardness. The primary focus of this talk will be on the chemical, structural, and mechanical design of such boride layers for severe operating conditions of various engine and tooling applications. Initial test results from a variety of bench-top tribotest machines will also be presented to demonstrate the much superior tribological properties for such boride layers over a broad range of test conditions.
4:10 PM E3-2/G2-2-8 A study on tribological behavior of arc-coated Ti-Al-N films on AISI 4340 alloy steel for automotive application
C.H. Hsu (Tatung University, Taiwan); C.K. Lin (Feng Chia University, Taiwan); D.W. Lai (Tatung University, Taiwan); K.L. Ou (Taipei Medical University, Taiwan)

This study utilized cathodic arc evaporation method to coat Ti-Al-N films on AISI 4340 steel for evaluating the feasibility of prolonging the use-life in the application of landing gears and truck parts. SEM, XRD, and TEM were used to confirm the morphology and structure of the coatings, and some coatings properties, such as adhesion, hardness, Young’s modulus, residual stress, and friction coefficient were all analyzed. The results showed that TiAlN film was indeed a single phase of FCC structure. The TiN/TiAlN multi-layered films had a good adhesion (HF1), high hardness (36.5 GPa), Young’s modulus (461 GPa), and appropriate residual stress (-5.68 GPa). Moreover, the optimum coatings achieved a remarkable reduction in the steel friction coefficient from 0.81 to 0.45.

4:30 PM E3-2/G2-2-9 Predicting lifetime of silver and gold coating depending on their thickness, stress and environmental conditions
Olivier Perrinet (LTDS, France)

The fretting wear phenomenon in electrical contacts is a plague in many applications, especially in the automotive industry, but also in other machines exposed to vibration. It induces severe electrical distortions, high electrical contact resistance and micro cuts.

This has led to the development of numerous coating systems consisting of pure metallic materials, noble and non-noble, doped as well as soft coatings.

Five coating systems were studied: a bronze–nickel–with different types of doped silver coating system and a bronze–nickel–with different types of doped gold coating system.

Using this apparatus, most of the physical conditions, such as relative humidity, temperature, frequency, relative displacement and normal force, can be precisely controlled and monitored.

We have observed and understood the kinetics of wear in connection, disconnection and reconnection simulation of electrical connector. This approach is applied to analyze hard coating wear mechanisms focusing on abrasion and oxidation phenomena.

4:50 PM E3-2/G2-2-10 Understanding durability of lubricant/DLC coating interface
Louise Austin, Tomasz Liskiewicz, Anne Neville (Leeds University, UK); Roel Tietema (Hauzer Techno Coating, BV, Switzerland)

DLC coatings are recognised as a promising way to reduce friction and increase wear performance of automotive parts and are currently being introduced for some engine and transmission components. DLC coatings, especially hydrogenated and doped with W or Si DLC coatings, provide new possibilities in improving tribological performance of automotive components, beyond what normally can be achieved with lubricant design only. However, currently used lubricants have been originally designed for metallic surfaces and there is a lack of knowledge on tribological behaviour of DLC coatings when lubricated with these oils, which limits their use in practical applications.

In this project, a W doped DLC coating is tested in lubricated contact simulating the engine tap/follower interface. The role of lubricant/surface interactions is investigated experimentally against a steel counterface. The tribofilm formation process is characterized chemically and mechanically using EDX mapping, XPS and nanoindentation. A link between the tribofilm structure/composition and tribological performance is studied. Hardness and elastic modulus are mapped within the contact area showing the evolution of the tribofilm mechanical properties. The f riction process is related to the dynamics of tribofilm formation and tribofilm time dependence is investigated. The emphasis of the paper is on how the coating structure and composition can be adapted for optimal interaction with fully formulated lubricant to enhance the tribological “system” performance.

5:10 PM E3-2/G2-2-11 From DLC to Si-DLC based layer systems with optimized properties for tribological applications
Dieter Hofmann, Stefan Kunkel (AMG Coating Technologies GmbH, Germany); Klaus Bewilogua, Ralf Wittorf (Fraunhofer IST, Germany)
Diamond-like carbon (DLC) coatings are used in many industrial applications like valvetrain-, fuel injection- and piston-systems etc.. For DLC (a-C:H) coatings, prepared by a magnetron based technique using graphite targets, high indentation hardness values of more than 40GPa were achieved. The wear resistance, the microhardness and the coefficient of friction are shown as a function of the hydrogen concentration in the coatings. In order to reduce the coefficient of friction even more and to increase the operation temperature of the coatings from about 350°C for DLC to near 500°C, a new Si-DLC based layer system was developed using a special magnetron sputter target configuration. This Si-DLC based layer system combines the benefits of a reduced coefficient of friction with a high wear resistance. The DC magnetron based production method allows the deposition of Si-DLC coatings in a wide range of compositions with 5 to 25 at.% Si at low hydrogen contents down to 5 at.%. The new Si-DLC based coatings show favorable conditions for present and future industrial applications.
Time Period TuA Sessions | Abstract Timeline | Topic E Sessions | Time Periods | Topics | ICMCTF2012 Schedule