PacSurf2024 Session NM-WeP: Nano and 2D Materials Poster Session

Wednesday, December 11, 2024 4:00 PM in Room Naupaka Salon 1-3
Wednesday Afternoon

Session Abstract Book
(293KB, Oct 10, 2024)
Time Period WeP Sessions | Topic NM Sessions | Time Periods | Topics | PacSurf2024 Schedule

NM-WeP-1 Introduction to Measurement Uncertainty Evaluation Method and Results of Silicon Nitride Thin Film Layer Thickness and Complex Dielectric Constant
Yong Jai Cho, Won Chegal (Korea Research Institute of Standards and Science)

SE (Spectroscopic Ellipsometer) has excellent measurement resolution, but measurement quality control of SE requires careful attention because measurement uncertainty can be easily affected by small changes in the device. For SE measurement quality control, thin film layer thickness certified reference materials are mainly used. SE has the advantages of being non-destructive, ultra-fast, and non-contact, but also has excellent high-precision characteristics that can detect a single atomic layer even before it is completely grown, so demand is increasing as a core measurement equipment for the semiconductor device manufacturing process. As semiconductor device manufacturing technology has recently developed due to the complexity of semiconductor device structures, the introduction of atomic layer-level processes, and the introduction of new materials, there is a need to improve quality control of TTTM (Tool-To-Tool Matching) related to measurement uncertainty. Therefore, in order to improve the measurement quality control level of SE equipment for semiconductor processing, it is necessary to develop higher quality thin film layer thickness certified reference materials. As a first research step, our research team developed a unified uncertainty evaluation method for the measurands of various types of rotating-element spectroscopic ellipsometers with excellent real-time measurement performance[1]. This method allows the measurement uncertainty of ellipsometric transfer quantities (e.g. Psi and Delta) to be calculated directly from observed ellipsometric transfer quantities, so there is no need for the analysis results of unknown optical properties of the sample required to calculate the measurement uncertainty. As a second research step, we developed a method for assessing uncertainty in the values ​​of unknown optical properties of the sample, obtained using a nonlinear least-squares fit from the spectra of the observed ellipsometric transfer quantities[2]. The implicit function theorem was adopted to describe the propagation of uncertainty for nonlinear least-squares calculations[3]. We would like to introduce the method and results of applying the developed uncertainty evaluation method to the uncertainty evaluation of the thin film layer thickness and complex dielectric constant of silicon nitride thin film sample obtained through SE.

References

[1] Y. J. Cho, W. Chegal, J. P. Lee, and H. M. Cho, Opt. Express 24 26215 (2016).

[2] Y. J. Cho and W Chegal, Opt. Express 29 394428 (2021).

[3] J. A. Fessler, IEEE Trans. Image Processing 5, 493 (1996).
NM-WeP-2 A New Tool for Single Ion Implantation and Nanoscale Materials Engineering: System Design and Source Development
Paul Blenkinsopp (Ionoptika Ltd., UK); Kate McHardy (Ionoptika, Ltd.); Gianfranco Aresta (Ionoptika Ltd., UK)

Quantum computing is the next great frontier of science. It has the potential to revolutionize many aspects of modern technology, including digital communications, “quantum-safe” cryptography, and incredibly accurate time measurements.

Single impurity atoms in semiconductors are receiving attention as potential quantum technologies, and proof-of-concept devices have shown promise. However, such devices are incredibly challenging to manufacture, as single atoms must be placed within ~ 20 nm of each other within a pure 28Si matrix.

All working devices thus far have been fabricated using hydrogen lithography with an STM followed by atomic layer deposition. This is labour-intensive and requires several days of meticulous preparation to create just a single quantum bit (qubit). Real-world devices will require arrays of hundreds or thousands of impurity atoms, highlighting the requirement for a scalable method of positioning single atoms with nanometer precision.

We report on a new commercial instrument for the fabrication of quantum materials and devices via single ion implantation.

The instrument features a high-resolution mass-filtered focused ion beam (FIB), a high-sensitivity deterministic implantation system, 6-inch wafer handling, and a high-precision stage. The deterministic implantation system allows single ion implantation with confidence levels as high as 98%.

The ion dose delivered to the sample can be adjusted across a wide range, providing many nanoscale materials engineering capabilities in a single tool, from single ion implantation to direct-write capabilities such as isotopic enrichment and targeted ion-implantation of nanomaterials.

The liquid metal alloy ion sources, coupled with and mass filtered column will enable for the implantation of many different elements with isotopic resolution. Available sources include silicon, erbium, gold, and bismuth, while many others of technological interest are in development. We will report on the LMIG source development carried out at Ionoptika in collaboration with our partners.

NM-WeP-3 Graphene-Incorporated Dielectric Composites by Varying the Mixing Method and Degree of Oxidation of Graphene
So-Yeon Jun, Kwangsin John Ahn, SeGi Yu (Hankuk University of Foreign Studies)

Graphene-incorporated dielectric composites by varying the mixing method and degree of oxidation of graphene

So-Yeon Jun, Kwangsin John Ahn, and SeGi Yu

Department of Physics, Hankuk University of Foreign Studies, Yongin 17035, Republic of Korea

To obtain high-performance dielectric properties of dielectric composites, graphene and barium titanate (BaTiO3, BTO) fillers were mixed in the polymer matrix, by varying the degree of reduction of graphene and the mixing method. Two kinds of graphene materials, i.e., graphene oxide (GO) and reduced graphene oxide (rGO); and two kinds of mixing methods for graphene and BTO, i.e., encapsulation of BTO in graphene and subsequent mixing, and simple mixing of BTO and graphene in the polymer matrix. This yielded to four kinds of graphene-incorporated samples, which was compared with the reference sample, i.e., a sample with only BTO fillers in the polymer matrix without graphene. Encapsulation process was performed by the self-assembly of positively functionalized BTO and negatively functionalized GO. After the encapsulation, GO-encapsulated BTO fillers were chemically reduced to become rGO-encapsulated BTO fillers [1,2]. All the four graphene-incorporated samples exhibited better dielectric constant values, i.e., 1.5 to 2.2 times higher than the reference sample. It was thoughted to be caused by the presence of graphene via the interfacial polarization or micro-capacitor effects [1]. However, the increase in dielectric loss, which had frequently occurred for the simple mixing cases of conducting nano-fillers, was successfully suppressed for the encapsulated samples. Here, the dielectric loss was controlled under lower 20%, which was caused by removal of free graphene platelets during the chemical process of the encapsulation [2]. The best performance one is the encapsulation method for rGO material. The next one is GO encapsulation case. The highest enhancement of 120% in the dielectric constant and moderate dielectric loss was obtained for rGO-encapsulation case. Therefore, we can say that encapsulation of BTO in graphene is very promising mixing method for high-performance polymer-based dielectric composite materials.

References:

[1]S.-Y. Jun et al., Carbon 199, 23 (2022).

[2]S.-Y. Jun et al., Mater. Chem. Phys. 255, 123533 (2020).

View Supplemental Document (pdf)
NM-WeP-4 Deep Learning-Based Prediction of Adsorption Energies for MoO₂Cl₂ Precursor on SiO₂ Surface Using Density Functional Theory
Do-Hyun Kwon, Jeong-Myung Lee (Korea University of Technology and Education); Jason Kim (Pohang University of Science and Technology (POSTECH)); Yeong-Cheol Kim (Korea University of Technology and Education)

A search for appropriate adsorption geometries of a MoO₂Cl₂ precursor on an -OH terminated β-SiO₂ surface was conducted using a deep-learning approach. The adsorption geometries were configured by translating and rotating the precursor located near the surface. A deep-learning model was developed to learn important properties of the adsorption geometries; the model consists of three main units to learn positional features of the precursor atoms, to learn distance features among the precursor and surface atoms, and to predict the corresponding adsorption energy. A dataset of adsorption geometry and the adsorption energy pairs was collected by grid search. Using this dataset, the model was trained to predict the adsorption energies with minimal error and optimized to achieve a root mean square error (RMSE) of less than 0.011%. Energetically more favorable adsorption geometries were found using the trained model. By inputting arbitrary adsorption structures into the trained model and obtaining the predicted adsorption energies, recommendations for energetically stable adsorption structures were received. Through actual calculations, it was confirmed that the model could identify energetically stable adsorption structures that were not included in the dataset. The proposed method is applicable to finding appropriate adsorption geometries of other types of precursors and surfaces.

NM-WeP-5 Induced Self-Assembly of Small (3 - 5 nm) Nanoparticles Into Flexible Nanofilms at Air- and Oil-Water Interfaces
Hannah Cameron, Yuwei Zhang, Kate Leslie, Bryn Scott, Isabel Curtis, Leah Gamble, M.-Vicki Meli (Mount Allison University)
Thin-film assemblies of gold nanoparticles (AuNPs) at the liquid interfaces have been an exciting research area over the past decade due to their promising applications in optics, sensors, shape-shifting and meta-materials, and catalysis. Autonomous self-assembly at such interfaces is an attractive method of synthesizing these superstructures, however this is a complex process that has proven to be difficult to control. Small AuNPs with core sizes <10 nm pose greater difficulties than larger AuNPs because they have a small free energy of adsorption that is comparable to their thermal energy. Therefore, there are few published examples of the self-assembly of such AuNPs at the liquid-liquid interface. The present research analyzes the effects of various experimental parameters on the adsorption of ~3 nm AuNPs to the oil–water interface, including ligand shell composition, alcohol additive structure and amount, oil phase composition and the phase of NP introduction. Film quality is qualitatively assessed and compared with a recent thermodynamic model to elucidate the primary driving forces of adsorption. Films with tunable optical density ranging from lightly coloured to gold and lustrous, are obtained with variation over a single parameter. Determining approaches that promote the adsorption of 3 nm AuNPs to an aqueous interface and furthering the understanding of its thermodynamic mechanism is necessary to gain precise control and to work towards the industrial use of such thin films. View Supplemental Document (pdf)
NM-WeP-6 Molecular Structure and Vapor Pressure of Molybdenum Pentachloride Using Ab-Initio Thermodynamics
Na-Young Lee (Korea University of Technology and Educaiton); Sun-Hye Kim, Jong-Yoon Kim, Yeong-Cheol Kim (Korea University of Technology and Education)
This study aims to elucidate the molecular structure and vapor pressure of molybdenum pentachloride in the gas phase using ab-initio thermodynamics. Molybdenum pentachloride can exist as MoCl5 (monomer) and/or Mo2Cl10 (dimer). The monomer is thermodynamically favored above 215 K, but Cl-Cl bond breakage is required to dissociate a dimer into two monomers. This suggests that the dimer is kinetically favorable even above 215 K, and the calculated dimer vapor pressure agrees well with the experimental data.
NM-WeP-7 Isotropic Atomic Layer Control of 2d Ws2 Using Organic Solvent Vapor
Hye Won Han, Ji Eun Kang, Ji Min Kim, Geun Young Yeom (Sungkyunkwan University)

Two-dimensional transition metal dichalcogenides (TMDs) exhibit diverse electronic and optoelectronic properties depending on their thickness, making precise layer control essential for their integration into advanced materials and devices. Atomic layer etching (ALE) techniques are crucial for achieving such precise thickness control and can be performed using either plasma or thermal methods. Previous studies have primarily focused on radical adsorption and ion desorption processes to enable anisotropic etching. However, with the evolution of device structures into three-dimensional configurations, isotropic etching has become increasingly important. In this study, we introduce isotropic thermal ALE of WS2 using organic solvent vapors. The ALE process consists of the adsorption of reactive radicals generated by oxygen plasma, followed by exposure to organic solvent vapors for desorption. This approach not only enables isotropic etching but also allows for damage-free processing, offering a significant improvement over conventional etching techniques. Additionally, we compare the etching performance based on organic vapors’ chemical structures and process temperatures, highlighting their differences in reactivity and volatility during the etching process. By providing precise layer control of WS2, this study advances the integration of TMDs into next-generation material and device technologies, marking a significant advancement in the field of advanced materials research.


NM-WeP-8 Uniform Vertical Doping of TMDC Materials via 
Jimin Kim, Jieun Kang, Hyewon Han, Geunyoung Yeom (Sungkyunkwan University)

Two-dimensional (2D) semiconductors, with their electrical and optical properties varying depending on thickness, are gaining recognition as key materials for future semiconductor technologies. To improve the properties of 2D materials Researchers are focusing on precise thickness control, large-scale production, and doping techniques. Doping, in particular, is an effective technique for adjusting the electrical behavior of 2D semiconductors, but conventional doping methods like ion implantation often damage the delicate and thin 2D semiconductors. To address this problem, alternative surface treatments such as plasma-based radical adsorption, liquid solution spin coating, and immersion techniques have been explored [1]. However, these approaches primarily modify the surface and become less effective as the material's thickness increases. To overcome the challenge of achieving uniform vertical doping, this research introduces an innovative cyclic doping technique utilizing a specialized transfer process. This method enhances the consistency of doping across multiple layers while preserving the distinct layered structure of MoS2. The cyclic doping technique presents a promising solution to current challenges in doping efficiency and uniformity, marking a significant advancement in the precise manipulation of 2D materials for semiconductor applications.

Session Abstract Book
(293KB, Oct 10, 2024)
Time Period WeP Sessions | Topic NM Sessions | Time Periods | Topics | PacSurf2024 Schedule