ICMCTF 2026 Session MC3-2-WeA: Tribology of Coatings and Surfaces for Industrial Applications II

The deposition of diamond-like carbon coatings is an established approach to enhance the service life of tribologically stressed components and tools for industrial applications. Due to today’s challenges of reduced lubrication, increased thermal and tribological loads as well as the demand for improved performance and service life, conventional and standardized existing thin films solutions are often limited in their wear-resistance and therefore provide insufficient protection. To overcome these challenges, tailored and application-specific coating systems have gained enormous interest in the field of carbon coatings. On the one hand the efficient deposition of these coating designs requires often a combination of advanced plasma technologies, as well as on the other side the possibility of chemically doping the amorphous carbon network to adjust the property profile. In this regard, the deposition of ta-C coatings by cathodic arc evaporation was found to be an excellent solution, which allows the adjustment of mechanical properties in a broad range as well as offers the possibility to combine different plasma technologies for the deposition of functional multi-layer designs. However, the key challenge is the evaporation of the carbon cathode, which was conducted by an industrial scale arc source (APA evaporator) using a dynamic controlled electro-magnetic field generated by a coil system to steer the arc spot motion and control the deposition conditions. This technology enables the modification of the tribological properties for the running-in phase and the “stationary” wear behavior by adjusting the coordination of the carbon network (sp³/sp²-ratio) as well as the chemical composition. In addition, the results reveal the possibility of controlling the intrinsic residual stresses of ta-C coatings to improve the coating adhesion. Furthermore, tailoring the properties was conducted by doping small amounts of Si in ta-C coatings for increasing the thermal stability, which therefore extends the application field of the coating systems.

This paper presents low-friction coating technologies for automotive tribology applied over the past 20 years. In the era of eco-friendly vehicles, particularly electric vehicles (EVs), it is essential to develop suitable coating technologies. Hyundai Motor Group has forecasted mobility trends for 2035: strong HEVs will account for 23% in 2035 (16% in 2024), plug-in HEVs 26% (8%), and battery EVs 38% (13%). By 2035, eFuel capacity is expected to increase from 3 billion liters to 100 billion liters. Global coating companies are developing technologies using hybrid process, low temperature coating process for polymer material, high ionization and high speed. Oerlikon-Balzers has introduced ta-C coatings for polymer materials, as well as MoN and ta-C coatings for automotive components. As a major research institution, Fraunhofer IWS in Germany presented Si- and B-doped ta-C coatings for applications up to 500 °C. RWTH Aachen University’s IOT developed coatings with a graded structure, consisting of S-rich and Mo-rich layers on CrAlN, to achieve low friction on plastic substrates. Recent developments in low-friction coatings presented at ICMCTF were analyzed, and the findings are included in this work. In Korea, R&D efforts focus on developing ultra-low friction coatings for extreme conditions, such as those found in EV components. Current coatings exhibit a coefficient of friction (CoF) of 0.05, while ultra-low friction coatings (CoF 0.01) include nitrides and ta-C doped with elements such as ZrCuSi, ZrMoTi, MoZrTiSi, and ZrMoTiCuSi. To address the corrosion issues of SiO-DLC caused by bioethanol fuels, ta-C coatings have been successfully applied, demonstrating high hardness (66 GPa), low friction (CoF 0.05), thermal resistance up to 500 °C, and excellent corrosion resistance. Furthermore, to enhance the frictional performance of coatings, electrochemical polishing technique (DLyte) has been employed, resulting in a significant reduction in surface roughness (Ra from 0.4 μm to 6 nm).

Despite the long legacy of carbon coatings in the PVD world, there are still many possibilities to stretch the boundaries of what is possible. With the new coating platform INSPIRA Carbon Mega we were able to develop a new PVD / PACVD coating machine reducing significantly machine production costs and coating temperature at the same time. A new, fast temperature measurement that allows an accurate in situ temperature indication on the turning part during process will be presented and gives a new dimension of insights in the design of coating process ensuring not to overheat sensitive substrates even in short periods of the process. The machine can provide the whole range of smooth carbon coatings from WCC to DLC to hydrogen free DLC coatings with up to 40 GPa hardness with low dependence on loading geometry. Additionally, a new black coating with extremely low L-Value and high hardness is available on this machine and will be presented.

Metal deposition processes for component repair are gaining attention as a practical alternative to replacement. Yet, welding-based methods can alter microstructures and reduce mechanical integrity, especially in high-carbon steels. Such effects are critical in components exposed to elevated temperatures and demanding service conditions. In this study, the effectiveness of boriding as a post-conditioning treatment to improve wear resistance and reduce tribological heterogeneity is investigated, with special attention to its stability under long-term high-temperature exposure. A repair process based on welding was simulated on AISI H13 tool steel. AISI 308L austenitic stainless steel and ERNiFeCr-2 alloys were used as filler materials for the restoration using the GTAW technique. After metal deposition, a pack-boriding treatment was applied to form a continuous boride layer over the repaired surfaces. Half of the borided samples were exposed to 700 °C for 240 h to evaluate their thermal stability. Surface hardness, coating adhesion, and tribological performance were characterized before and after thermal exposure, both in the repaired and non-repaired regions, using nanoindentation, scratch testing, and dry reciprocating sliding tests. Surface damage and wear mechanisms were analyzed by scanning electron microscopy, and the wear volume was quantified through optical profilometry. Boriding proved effective in reducing mechanical property mismatches between the base and repaired regions and in enhancing the tribological performance of repaired H13 steel, even after prolonged high-temperature exposure. The treatment was particularly beneficial for samples repaired with stainless steel filler metal.