AVS2017 Session TR+AC+TF+VT-ThM: Lubricant, Coatings, and Biotribology

1. M. Kano, J. M. Martin, K. Yoshida, M.I. De Barros Bouchet, Friction J., 2 (2) (2014) 156.

2. M.I. De Barros Bouchet, J.M. Martin, J. Avila, M. Kano, K. Yoshida, T. Tsuruda, S. Bai, Y. Higuchi, N.i Ozawa, M. Kubo and M. C. Asensio, Scientific Reports, 2017 (DOI: 10.1038/srep46394).

The friction phenomenon is a complex manifestation of the nature. In spite of phenomenological laws can describe the friction force at different scales, the fundamental physical understandings of such a phenomenon do not have consensus. Phenomena such as phononic, electronic, magnetic, and also electrostatic effects and models were developed in order to explain the meta- and nano-friction behavior of materials. In this work, we report the friction behavior of a diamond spherical dome sliding on different amorphous carbon thin films containing different amounts of hydrogen and/or deuterium inspecting at the meta-nanoscale indentation. Two important situation are reported. Firstly, for samples where hydrogen was replaced by deuterium in the thin film bulk, the friction coefficient decreases for increasing deuterium included in the carbon underneath structure. Secondly, for samples where hydrogen content is increased on the surface, the friction coefficient decreases with the increasing of the ratio H/C at the surface. In this paper, we discuss two different physical mechanisms describing these peculiar experimental results: dissipation effects associated with phonon coupling and van der Waals forces contributions coexisting and determining the friction behaviour of a-C:H/D for the cited studied situations.

Among the variants of diamond-like carbon films developed for the ever-increasing performance and durability requirements of tribo-mechanical applications, silicon oxide-containing hydrogenated amorphous carbon (a-C:H:Si:O) is of interest as it exhibits good tribological performance across a broader range of environments compared to hydrogenated amorphous carbon, and higher thermo-oxidative stability. However, the scientific basis for this improved behavior is not established. In this work, we develop a fundamental understanding of the structural transformations occurring in a-C:H:Si:O when sliding against steel in different environments (from high vacuum to controlled hydrogen and oxygen pressures). The results of tribological experiments revealed that upon increasing the oxygen pressure in the experimental chamber from 10 mbar to 1000 mbar, the coefficient of friction increased from 0.02±0.01 to 0.06±0.01, whereas upon increasing the hydrogen pressure from 50 mbar to 2000 mbar, the coefficient of friction decreased from 0.08±0.01 to 0.02±0.01.The subsequent near edge X-ray absorption fine structure (NEXAFS) spectroscopic measurements and X-ray photoelectron spectroscopy (XPS) analyses provided insights into the structural transformations and chemical reactions occurring in a-C:H:Si:O upon sliding. Independently of the gas, a stress-induced conversion from sp³- to sp²-bonded (disordered) C-C bonds occurs. When sliding in hydrogen, the newly-generated, strained sp² carbon layer reacts with hydrogen molecules to form a hydrogenated amorphous carbon interfacial material. Upon increasing the hydrogen pressure, the fraction of C-H bonds increases in the near-surface region of the wear tracks formed on a-C:H:Si:O. This is proposed to progressively lower the shear strength of the material at the sliding interface, thus resulting in a decrease of friction with hydrogen pressure. When sliding in oxygen, the dissociative reaction of oxygen molecules with strained sp² C-C bonds leads to the formation of C=O groups. Additionally, increasing the oxygen pressure during tribological testing leads to an increase in oxygen concentration in the near-surface region of a-C:H:Si:O together with an increase in the fraction of Si atoms in high oxidation states. These surface chemical changes and structural transformations are proposed to increase friction with oxygen pressure by progressively increasing the shear strength of the material generated at the sliding interface.

Friction is a pervasive problem, by some estimates consuming about 5% of the GDP of the economies of the developed world, and a recent analysis has indicated that about one third of the fuel energy in automobiles goes to overcoming frictional losses. While the importance of minimizing friction can be traced back at least as far as the tomb of Tehuti-Hetep, circa 1880 B.C, where a man can be seen pouring a lubricant to assist moving a statue, there are still many unknowns in the field of tribology which encompasses friction as well as other critical processes such as wear and lubrication. For many of the phenomena in tribology there are still numerous unknowns. When it comes to biological systems most work to date has assumed that different mechanisms are taking place than occur for inorganic systems. While there are differences, there are also significant similarities particularly in implants when inorganic and biological meet. We have recently shown that for metal implants in-vivo the same type of graphitic materials that appear in many areas ranging from heterogeneous catalysis to oil lubrication are present. Beyond just lubrication, corrosion of these materials is not special to biological systems, but has strong similarities to established factors such as grain boundary precipitation and a significant role for molybdenum as reducing the occurence of breakdown of the protective oxide film via complex processes involving solute trapping. These and related recent results will be described.