AVS2015 Session 2D+EM+MC+MI+NS+SP+SS+TF-TuA: Electronic and Magnetic Properties of 2D Materials

Tuesday, October 20, 2015 2:20 PM in Room 212C
Tuesday Afternoon

Time Period TuA Sessions | Abstract Timeline | Topic 2D Sessions | Time Periods | Topics | AVS2015 Schedule

Start Invited? Item
2:20 PM Invited 2D+EM+MC+MI+NS+SP+SS+TF-TuA-1 Direct Capacitive Probe of Isospin Order in Graphene Bilayers
Andrea Young (University of California at Santa Barbara)
Bilayer graphene is a highly tunable electronic system in which electric fields can be used to control both the carrier density as well as the electronic structure. Like its monolayer cousin, the bilayer graphene Landau levels are characterized by approximate spin and valley degeneracy; unlike monolayer, however, the three dimensional structure of the bilayer allows control of the sublattice splitting with a perpendicular electric field. This feature has been used extensively to probe the phase diagram of interacting electrons, particularly within the zero energy Landau level, revealing a number of interacting states characterized by spin and/or valley order. Typically, however, the spin or valley order is inferred indirectly by varying conjugate fields and inferring the order from the resulting changes in conductivity. Here I will describe a technique capable of resolving layer-polarization directly through high sensitivity capacitance measurements. The measurements confirm the known features of the bilayer graphene phase diagram, while revealing several new phases and a series of sharp features associated with phase transitions between states of different layer polarization. These features suggest a new mechanism for inversion symmetry breaking in Bernal stacked bilayer graphene.
3:00 PM 2D+EM+MC+MI+NS+SP+SS+TF-TuA-3 Patterning Hydrogenated Graphene via Electron Beam Irradiation
Woo-Kyung Lee, Keith Whitener, Jeremy Robinson, Paul Sheehan (Naval Research Laboratory)

We demonstrate that electron-beam irradiation selectively removes hydrogen atoms from hydrogenated graphene (HG) prepared by the Birch reduction.1 Hydrogen removal can pattern the surface with two different functionalities. First, we show that partially-hydrogenated graphene (Phg) on a SiO2 substrate is ferromagnetic, and that the local magnetic strength can be tuned using e-beam irradiation. An e-beam lithography system enables us to modulate or eliminate the permanent magnetization over a large area to produce a patterned magnetic array. Secondly, since removal of the hydrogens converts the highly electrically insulating HG back into conductive graphene, we can write chemically isolated, dehydrogenated graphene nanoribbons (GNR) as narrow as 100 nm. These GNRs have a low sheet resistance (≥ 31.5 Kω/□), only 10x that of the pristine graphene, and their Dirac points before and after e-beam irradiation appear at comparable gate voltages.

1. W.K. Lee et al., Advanced Materials, 27, 1774 (2015).
3:20 PM 2D+EM+MC+MI+NS+SP+SS+TF-TuA-4 Large-Area Low-Pressure Synthesis of Single-Layer MoS2 Films and Schottky-Barrier Formation upon Metal Deposition
Michael Gomez, Joseph Martinez, Michael Valentin, Ludwig Bartels (UC Riverside)

Using a high vacuum CVD process we are able to synthesize large are monolayer MoS2 films. Organic chalcogen precursors are released into the growth chamber and react with a Mo filament creating films up to 2cm­2 in size that are uniform and free of oxides. The films have pronounced photoluminescence intensity and are in Raman spectroscopy indistinguishable from exfoliated material. Metal contact formation to these films was investigated under UHV conditions utilizing X-Ray Photoelectron Spectroscopy . These measurements permit us to follow the formation of a Schottky Barrier with increasing metal film thickness on the Angstrom scale. We utilize core level spectroscopy to indicate the evolution of the MoS2 valence band under metal deposition.

3:40 PM BREAK
4:20 PM Invited 2D+EM+MC+MI+NS+SP+SS+TF-TuA-7 Accelerating the Discovery of Alternative Fuel Catalysts through Intelligent Computational Framework
Altaf Karim (COMSATS Institute of Information Technology, Pakistan)

In today’s modern world of high performance computing, properties of materials can be predicted with high accuracy before these materials are ever made. In this scenario my focus has been on the development of state of the art computational framework based on intelligent/ smart self-learning algorithms for the design and discovery of catalytic materials. By giving some examples, I will describe how this enterprise of the predictive multi-scale modeling/simulation has been passing through the stages of its evolution and how these complex algorithmic species integrated themselves into an intelligent python, which is helping scientists design & discover new materials for alternative fuel catalysis. In practice, our computational framework develops databases of candidate catalysts. Further this framework enables a set of algorithms to screen across a broad range of multi metallic catalytic materials with variable reactivity, selectivity, and stability while searching for materials with desired combination of properties required for the optimal catalytic performance for alternative fuel production. I would also explain that how our computational tools in catalyst design deal with the multi-component microstructures of catalysts composed of multi-element nano chunks. In order to tune up the rate limiting processes we can take advantage of the multi-element nano chunks. For example, on many catalytic surfaces the diffusion is rate limiting process for larger organic molecules. To enhance the diffusion such molecules on such surfaces, nano chunks of other materials (on which the diffusion of the organic molecules is comparatively higher) can be integrated in the catalyst’s surface, which improves the overall performance of the catalyst in terms of overall reactivity and also selectivity. In addition to that our tools also help us to filter out, from the databases, stable multi-component microstructures of artificially engineered catalysts.

5:00 PM Invited 2D+EM+MC+MI+NS+SP+SS+TF-TuA-9 Probing Massive Dirac Electrons in Bilayer Graphene
Feng Wang (University of California at Berkeley)
Electrons in monolayer graphene are described by massless Dirac electrons, which exhibit unique quantum phenomena due to the pseudospin and Berry phase of the massless electrons. In this talk, I will discuss our effort in probing massive Dirac electrons in gapped bilayer graphene. In particular, I will discuss the topologically protected 1D conducting channel at the domain boundary of AB-BA bilayers, which can be attributed to the quantum valley Hall edge states in gapped bilayer graphene.
5:40 PM 2D+EM+MC+MI+NS+SP+SS+TF-TuA-11 Combining Photoemission and Photoluminescence Microscopy to Study Substrate Transfer Process Effects in Chemical Vapor Deposited MoS2 Monolayers
Olivier Renault, Mathieu Frégnaux (Univ. Grenoble Alpes/ CEA, LETI, MINATEC Campus, France); Joël Bleuse (Univ. Grenoble-Alpes & CEA-INAC, France); HoKwon Kim (Univ. Grenoble Alpes/ CEA, LETI, MINATEC Campus, France); Damien Voiry, Manish Chhowalla (Rutgers University)

Within the perspective of integrating two-dimensional transition metal dichalcogenides (2D TMDs) such as molybdenum disulfide (MoS2), into devices, it becomes of utmost importance to assess the influence of each step of the device fabrication process on the optical and transport properties of the MoS2 single layer (1L) domains. Particularly at the deposition stage the properties may be influenced by substrate effects [1], and later, transfer processes may further alter the desired properties of TMDs. This requires effective microscopic characterization techniques.

We present a characterization method combining photoemission microscopy (XPEEM and Kpeem) and photoluminescence microscopy to compare the structural, optical and electronic properties of both as-deposited and transferred MoS2 1L domains onto different substrates. XPEEM is used with laboratory sources in both direct space imaging for work function and core-level mapping [2] and particularly in the momentum microscopy mode (k-PEEM) to perform parallel angular imaging and retrieve the band structure in a one shot experiment [3]. Micro-photoluminescence spectroscopy at low (5K) and room temperature is used to detect the specific radiative recombination that occurs in MoS2 1L (direct band gap semiconductor behavior) and to evidence the eventual presence of midgap states caused by process-induced defects. The results of both characterization techniques will be presented for MoS2 1L domains transferred onto silica and gold substrates highlighting the roles of substrate nature (metal or insulant), surface roughness, and the presence of structural defects whether induced by the preparation process or intrinsic such as grain boundaries.

[1] Jin et al. Phys. Rev. Lett. 111 (2013), 106801.

[2] Kim, Renault, et al. Appl. Phys. Lett. 105 (2014) 011605.

[3] Mathieu et al., PRB 83 (2011) 235436.

Time Period TuA Sessions | Abstract Timeline | Topic 2D Sessions | Time Periods | Topics | AVS2015 Schedule